Rendering the arylation intramolecular also results in phenomenologically simpler reaction kinetics, and overall these features have facili tated a detailed study of linear free energy relationships, kinetic isotope effects, and the first quantitative experimental data on the effects of aryl electron demand and conformational freedom on the rate of reductive elimination from diaryl gold(III) species. The turnover limiting step for the formation of a series of fluorene derivatives is sensitive to the electronics of the arene and changes from reductive elimination to complexation for arenes bearing strongly electron withdrawing substitu ents ( >0.43). Reductive elimination is accelerated by electron donating substituents ( = 2.0) on one or both rings, with the individual values being additive in nature.
Their Symptoms and Treatment was published in Calcutta in 1912. At some three hundred fifty pages, the book was meant to be a handbook to the theory and practice of mental disease in India. Overbeck Wright acknowledged in the book’s preface that the book made ‘no pretense of being anything but a compilation’.
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